First recorded by Cilla Black (US #95/UK #9 January 1966).
Also recorded by Jerry Butler (May 1966, released December 1967), Dee Dee Warwick (May 1966, released 1967).
Other hit versions by Cher (US #32/CAN #36 June 1966), Dionne Warwick (US #15/R&B #5 December 1966).
From the wiki: “‘Alfie’ was written by Burt Bacharach and Hal David to promote the 1966 film Alfie. Although Bacharach and David suggested ‘Alfie’ be recorded by Dionne Warwick, their most prolific interpreter, Paramount felt the film’s setting demanded the song be recorded by a UK singer. Accordingly, the initial invitation to record ‘Alfie’ was made to Sandie Shaw who had had a UK #1 hit with the Bacharach/David composition ‘(There’s) Always Something There to Remind Me’. When the invitation to Shaw was declined ‘Alfie’ was offered to Cilla Black, who had also had a previous UK #1 with a Bacharach/David song: ‘Anyone Who Had a Heart’.